Relaxation Phenomenon

relaxation phenomenon, in physics and chemistry, an effect related to the delay between the application of an external stress to a system—that is, to an aggregation of matter—and its response. It may occur in nuclear, atomic, and molecular systems. Chemists and physicists use relaxation effects to study processes that take only a fraction of a second. When an equilibrated nuclear, atomic, or molecular system is subjected to an abrupt physical change, such as a sudden rise in temperature or pressure, it takes time for the system to re-equilibrate under the new conditions. The relaxation effect may be caused by a redistribution of energy among the nuclear, electronic, vibrational, and rotational energy states of the atoms and molecules that constitute the system, or it may result from a shift in the ratio of the number of product molecules to the number of reactant molecules (those initially taking part) in a chemical reaction. The measurement of relaxation times can provide many insights into atomic and molecular structures and into the rates and mechanisms of chemical reactions.